Crafting a high-performance bushcraft knife requires a deep understanding of how forging and heat treatment influence the steel’s internal metallurgy and real-world durability.
This handbook serves as a comprehensive reference for bladesmiths and knife enthusiasts, consolidating technical knowledge from metallurgy, manufacturer datasheets, and field testing. We will explore each stage of the knife-making process – from high-temperature forging through quenching and tempering – and explain how these processes affect grain structure, carbide distribution, hardness, toughness, edge durability, and corrosion resistance.
Each section below is richly detailed with technical insights and includes diagrams, tables, and cited sources for further verification. Whether you are normalizing a 1095 blade or optimizing a stainless steel heat treat, this handbook will help you make informed decisions to produce reliable knives for harsh wilderness use.
Forging Temperatures and Steel Transformations
When shaping a blade by forging, steel must be heated into the proper temperature range to become malleable without damaging its internal structure. Forging temperature is typically within the austenitic phase region of the steel (around 870-1200 °C, depending on alloy) where the metal is red-hot and can be plastically deformed. It is critical to stay within manufacturer-recommended limits: working below the minimum forging temp risks cracks (the steel is too rigid), while heating above the maximum can cause hot shortness – a condition where the metal crumbles due to incipient melting or deleterious phase formation[1][2]. For example, many carbon/tool steels should not be forged above ~1200 °C (≈2200 °F); beyond this, low-melting constituents can liquefy at grain boundaries (“burning” the steel) leading to catastrophic failure[3]. Likewise, forging below the critical temperature can result in tearing or fracture instead of clean deformation[4][5]. Always consult the specific steel’s datasheet for its safe forging range. Carpenter Technology warns that exceeding the upper forging limit can introduce incipient melt phases or excessive grain growth that are “very difficult, if not impossible to correct”[1][6].
During forging, the steel undergoes phase transformations that affect its microstructure. Most bushcraft knife steels are hypoeutectoid or eutectoid (≤0.8% carbon) alloyed steels, which means when heated above the A₃/Aᵗ (austenitizing) temperature, their ferrite/pearlite base structure transforms into austenite (a face-centered cubic phase that is softer and more formable). Forging in the austenitic range allows the steel to be shaped with reasonable force. In high-carbon steels (hypereutectoid >0.8% C), heating above A_c1 (~727 °C) forms austenite but excess carbon may remain as undissolved carbides until a higher A_cm temperature is reached. This is why a steel like 1095 might still show some magnetism (ferrite/carbide presence) until ~850 °C even though a lower temperature (780-800 °C) is sufficient to form austenite matrix for forging[7]. It’s generally unnecessary and harmful to push hypereutectoid steels to fully dissolve all carbides during forging; a lower forging temp yields a finer structure and avoids overheating the steel[8].
Notably, the mechanical deformation during forging can actually refine grain size if done properly. The process of dynamic recrystallization occurs in austenite at high temperatures under deformation: each hammer blow introduces new strain and can trigger the formation of fresh, smaller austenite grains even as you forge[9]. In practice, this means that a skilled bladesmith who forges at the correct temperature and uses sufficient force can avoid excessive grain growth – the continual regeneration of austenitic grains “prevents excessive grain growth at the high temperatures where forging…is usually done, around 2200 °F”[9]. However, this beneficial effect has limits. If the steel is soaked at high heat without deformation (for example, sitting too long in the forge), grains will begin to coarsen rapidly. Additionally, every time you reheat the steel, grain growth can resume once recrystallization is complete. Thus, the best practice is to forge at the lowest temperature that still permits good plasticity, minimize soak times, and perform repeated forging passes with intermediate reheats rather than one prolonged high-heat soak.
Avoiding overheating: It’s tempting to heat steel “as hot as possible” for easier hammering, but this trade-off sacrifices quality. Overheating leads to grain coarsening, heavy scale formation, and in extreme cases liquation of grain boundary phases (the aforementioned burning)[10][5]. Visually, overheating may be indicated by a sparking or crumbling surface. Such damage cannot be fully undone by later treatments. Instead, forge within the recommended range. For instance, Bohler/Uddeholm O1 tool steel (a popular bushcraft blade steel) is typically forged in the range of ~850-1050 °C, ensuring it never approaches its melting constituents’ point[1]. If you accidentally overheat (steel appears “wet” or starts sparking), it is wise to stop and normalize the blade (discussed below) to attempt grain refinement, but be aware that severely burnt steel may be irreparable.
Forging stainless steels: Martensitic stainless blade steels (e.g. 420HC, 440C, CPM S35VN) can also be forged, but they often have narrower forging ranges and lower hot ductility than simple carbon steels. High chromium content lowers the incipient melting point for certain phases and can cause grain boundary liquation if forged too hot[11][12]. Data show, for example, that common austenitic stainless (304) loses hot ductility dramatically above ~1150 °C due to either a minor melting phase or loss of grain boundary cohesion[13]. Martensitic stainless should generally be forged at the low end of its austenitic range and not overheated; some sources even recommend forging them in steps with frequent reheating and not above ~1050 °C for cutlery grades to avoid delta-ferrite formation or chromium carbide networks[14][12]. After forging, stainless blades usually require thorough annealing and normalization to relieve stresses (and to dissolve any unwanted delta ferrite). In summary, forging temperatures must be closely controlled. Use a thermocouple-equipped forge or temperature crayons if possible, watch the steel’s color (bright yellow but not white for most carbon steels; orange for stainless), and remember: never exceed the alloy’s limits. By adhering to proper forging temperatures, you ensure the steel’s internal structure remains primed for optimal heat treatment later.
Read more about: Forging temperature windows for knife steel
Grain Growth and Carbide Structure
Grain size is a pivotal factor in the toughness and strength of a knife blade. Fine-grained steel yields a tougher, more shock-resistant blade, whereas coarse grains can make the steel brittle and prone to catastrophic failure (chips or breaks) when stressed[15][16]. Grain growth refers to the enlargement of austenite grains when steel is held at high temperature. This growth occurs because larger grains consume smaller ones via boundary migration (atoms diffuse from the convex side of a boundary to the concave side)[17]. The driving force is reduction of total grain boundary area (which lowers energy). Unfortunately, grain growth is extremely sensitive to temperature – much more so than to time. For instance, in one study of 1060 carbon steel, raising the austenitizing temperature from 1400 °F (760 °C) to 1700 °F (927 °C) (for a short 6-minute soak) nearly tripled the austenite grain diameter, from ~33 µm to ~94 µm[18]. In contrast, extending the soak time at 1700 °F twenty-fold (from 6 minutes to 2 hours) increased grain size by a factor of only ~1.85 (from 94 µm to 174 µm)[19]. This illustrates that excessive temperature is far more damaging to grain size than moderate holding time[15][20]. The practical takeaway: do not austenitize or forge any hotter than necessary. Use just enough heat to achieve your desired transformation or deformation. Every 10-20 °C beyond the critical needed will promote more grain growth than dozens of extra minutes at a lower temperature[21].
Another key aspect is the role of carbide particles in pinning grain boundaries. In alloy steels, small carbides (such as chromium, vanadium, or niobium carbides) can inhibit grain growth by exerting a pinning force on moving boundaries. High-alloy steels used in knives often contain significant carbide volume. During heat-up, not all these carbides dissolve, especially if you use a conservative austenitizing temperature. The undissolved carbides effectively pin the austenite grain boundaries and prevent them from ballooning. As a result, many high-alloy steels can maintain fine grain size even when heated to relatively high temperatures. Metallurgist Larrin Thomas notes, for example, that steels like CPM Magnacut (rich in vanadium and niobium carbides) achieved an ASTM grain size of ~12 (very fine) even after austenitizing at 2150 °F (1177 °C)[22][23]. In his words: “the high-alloy steels…have enough carbide where the grains are very well pinned at typical forging temperatures”[22]. This means that simple carbon steels (e.g. 1080, 5160) are more prone to grain coarsening when overheated than modern powder metallurgy stainless or tool steels with heavy carbide fractions.
That said, any steel can develop coarse grains if grossly overheated. Visualizing grain size is possible by fracturing a hardened blade: a silky matte gray fracture indicates fine grains, whereas a sparkling crystalline fracture surface indicates large grains (this old bladesmith’s trick correlates with grain size). If a blade’s grain has grown too large, the knife tends to be brittle; large grains also reduce toughness and fatigue resistance[15]. Refining grain size is possible through thermal cycling (discussed in the next section). Another preventative measure is selecting a proper austenitizing temperature so as not to dissolve all carbides when not necessary. For example, 1095 high-carbon steel technically has an Acₘ (carbide dissolution completion) around 850 °C+, but blade smiths often harden it at ~800 °C. This slightly lower temperature leaves behind a bit of undissolved cementite which helps keep grains small and prevents the austenite from absorbing excessive carbon (excess carbon would just turn into retained austenite later)[8]. Alleima (Sandvik) cautions in its datasheets that “too high hardening temperature gives coarse structure, high austenite content (~30%), [and] few carbides”, resulting in poor hardness and wear resistance[8]. In other words, overshooting the recommended austenitizing temp can dissolve too many carbides (sacrificing their grain-pinning and wear-resistant benefits) and create an austenite that will transform incompletely (lots of retained austenite) and then yield coarser martensite upon quenching.
To summarize this section: grain growth is the enemy of a tough bushcraft knife. Avoid it by controlling temperature carefully. Fine carbides are your friends- they lock grain boundaries in place. Use alloy steels to advantage, but even with simple steels, you can manage grain size via proper thermal practices. If you suspect grain coarsening (perhaps due to an accidental overheat in the forge), normalization and cycling can often rescue the microstructure.
Read more about: Austenite grain growth in blades
Thermal Cycling and Normalization
Thermal cycling refers to the practice of reheating and cooling steel through phase transformations multiple times to refine its microstructure. In knife making, the most common form of thermal cycling is normalization, sometimes repeated in multiple cycles. Normalization typically means: heat the blade into the austenite range then let it cool in still air to below the transformation range (usually to room temperature). This transforms the austenite into a fine mixture of ferrite and pearlite. Each normalization can progressively refine grain size and also relieve stress from forging.
After heavy forging, a blade’s microstructure is non-uniform – it may have bands of pearlite, regions of Widmanstätten pattern, or simply large distorted grains from the last forging heat. Normalization homogenizes the structure: when you heat to form austenite, new austenite grains nucleate along the previous ferrite/pearlite boundaries. If done correctly, these new grains start small. Air cooling then produces fine pearlite within those austenite grains. A subsequent cycle will again form new austenite from that fine structure, usually yielding even finer grains. The result of 2-3 cycles is a very refined grain structure ready for hardening.
A proven recipe for high-carbon simple steels is a triple normalization at descending temperatures. For instance, 1095 carbon steel can be normalized in three steps: (1) heat to ~1650 °F (899 °C), air cool; (2) heat again to ~1500 °F (815 °C), air cool; (3) heat a third time to ~1350 °F (732 °C), air cool[24]. Each stage’s lower temperature ensures that excessive grain growth is avoided in later cycles, and the last cycle might be just above Ac₁ (so that only very fine austenite forms along remaining carbide particles). By the end, the grain size is greatly reduced from the as-forged state. The New Jersey Steel Baron datasheet for 1095 confirms this process, including soaking ~10-15 minutes at each normalization temperature for best effect[24]. Another example: for 5160 spring steel, one normalizing cycle at 1600 °F (870 °C) followed by an isothermal anneal or a subcritical cycle is recommended to reduce warping in quench[25] (this particular source suggests normalizing, then annealing at 1250 °F, then a “DET” cycle at 1380 °F to form a very fine ferrite-carbide mix[26] – a complex process aimed at extreme toughness). In most cases, a simpler approach suffices: if you forged the blade, a single normalization at or slightly above your final austenitizing temp can reset the grain. If the grain was grossly enlarged, consider a triple normalize as described to ensure maximum refinement.
Beyond normalization, other thermal treatments include annealing and stress relieving. Annealing typically involves heating to austenite and then very slowly cooling (often in a furnace) to produce coarse pearlite or spheroidized carbides. This yields a very soft metal for machining, but note: annealing tends to increase grain size (due to the slow cool) and is usually counterproductive to ultimate blade performance if done right before hardening (you’d want to normalize after an anneal to refine the grain again). Many knifemakers skip a full anneal and instead do normalization or a “subcritical anneal” (a soak just below Ac₁ to soften the steel without phase change). The goal, in any case, is to have a uniform microstructure with fine distribution of carbides before the final hardening heat. Thermal cycling accomplishes that by repeated phase changes.
Another concept is quench refinement or “thermal quenching.” Some blade smiths for high alloy steels will do a pre-quench from a lower austenitizing temperature to refine grain, then re-austenitize at the final higher temperature. For instance, Devin Thomas reported that pre-quenching certain high-alloy steels from ~1750 °F then re-hardening can reduce grain size further in steels like D2, M2, AEB-L[27]. This is an advanced technique that essentially forces a fresh martensitic structure, then new austenite nucleation for the final quench. It’s not commonly needed for simpler steels if you’ve normalized properly.
In summary, normalization and thermal cycling are invaluable for ensuring fine grain and relieving internal stresses prior to the critical quench. Even if you did not forge the blade (stock removal knife), a normalization cycle can be beneficial to refine the grain of barstock (some factory barstock comes with coarse structures from industrial processing). It’s standard practice at Yashar Survival to normalize blades after forging and before hardening. We document cycle temperatures and times in our shop logs, adhering to best practices and adjusting per steel type. The result is a blade that will have a more uniform response to hardening and superior toughness.
(Note: Always allow the blade to air cool to “black heat” (around 400 °C or below) between cycles. Handle carefully – even at 200 °C steel can be brittle from freshly formed phases. Also, if using anti-scaling compounds or foil during cycles, ensure the blade still gets sufficient air cool if normalization is intended – i.e., don’t leave it insulated in foil for the cooling.)
Find out more here: Normalization and thermal cycling after forging: when it fixes problems and when it does not
Austenitizing and Critical Soak Behavior
Austenitizing is the process of heating the steel to form austenite (the phase in which steel can be hardened by quenching). The temperature at which austenite begins to form is the critical temperature (Ac₁ for eutectoid start, Ac₃ for full transformation in hypoeutectoid steels). In practice, knifemakers choose a specific austenitizing temperature (often given by the steel supplier) that achieves the desired balance of hardness, toughness, and grain size. This temperature is often a bit above Ac₃ (for hypoeutectoids) or above Ac₁ but below Acₘ (for hypereutectoids) to ensure sufficient carbon in solution without incurring problems from excessive temperature.
When you heat to the austenitizing temp, you must also soak (hold) the steel for a certain time to allow transformation and homogenization. During the soak, several things happen: ferrite/pearlite transforms to austenite, carbides dissolve releasing carbon into solution, and the elements redistribute to reach equilibrium (or at least a consistent state). Critical soak behavior refers to how the steel responds during this hold – e.g. how carbides dissolve, how grain growth might initiate, how evenly temperature penetrates the cross-section, etc.
For thin sections like knife blades (3-5 mm thick or less), soak times are relatively short since heat penetrates quickly and diffusion distances are small. A typical soak might be 5-15 minutes at temperature for many carbon/alloy steels[28][29]. For instance, our heat treat of 1095 might call for 5-10 minutes at ~1475 °F (801 °C)[29], whereas a stainless like 440C might require 30 minutes at 1900 °F (1040 °C) because of its high chromium carbides that need time to dissolve. Always follow datasheet guidance for soak times based on steel type and thickness. As a general rule, high alloy steels need longer soaks (to dissolve carbides like V, Mo, Cr which diffuse slowly) and simple steels need only short soaks (carbon diffuses fast – in plain carbon steel, a few minutes is enough for full solution in thin cross-sections). Excessive soak time can coarsen the grain (see previous section), but manufacturers usually quote a safe soak duration that balances solution and grain growth.
Selecting the right austenitizing temperature is crucial. This choice controls how much carbon and alloy content is in the austenite. A higher temperature dissolves more carbides, yielding higher carbon austenite (and thus higher potential hardness after quench) – but it also risks more retained austenite and grain growth. A lower temperature leaves more carbides undissolved (limiting maximum hardness but improving dimensional stability and possibly toughness). For example, O1 tool steel can be hardened at 1475 °F or at 1550 °F; the higher temperature gives a harder as-quenched martensite but actually resulted in lower toughness in experiments[30]. In fact, Thomas et al. found O1 hardened at 1550 °F had significantly reduced impact toughness compared to 1475 °F, likely due to the higher carbon in solution and perhaps some retained austenite[30]. Thus, more is not always better. Each steel has an optimum range. As another example, 5160 spring steel (0.6% C, Cr alloyed) has an optimal austenitizing “sweet spot” around 840 °C (1545 °F) – heating much above ~850 °C gains no hardness but coarsens the grain and risks bainite formation on quench[31][32]. Alleima’s guide for its stainless knife steels similarly specifies heating “to the required hardening temperature (A) between 1050 and 1090 °C depending on grade” and emphasizes not exceeding that[33].
Depth of hardening is also decided here. If you have a thicker piece or lower-hardenability steel, a slightly higher austenitizing temp can ensure deeper penetration of hardness (by raising hardenability through more alloy in solution). But in thin knives, this is usually not a concern – any reasonable austenitize will through-harden a blade in oil or faster. So focus on grain size and retained austenite control when choosing temperature.
During the soak, ensure the furnace is evenly heated or, if in a forge, continuously and evenly heat the blade (do not leave part of the blade cooler, which could result in non-uniform structure). Many heat treat ovens benefit from a preheat (e.g. ramp to ~730 °C, hold, then ramp to austenitize) especially for high alloy steels to avoid thermal shock. Some datasheets for high-carbon tool steels recommend a two-stage austenitizing: hold at a lower temperature to equalize, then go to final temp[34]. This is less critical for small knives but essential for larger sections.
One must also consider atmosphere: at austenitizing heat, steel can decarburize quickly in open air, losing surface carbon and reducing hardness at the edge. Use stainless foil wraps, anti-scale coatings, or an inert atmosphere (if available) when soaking above ~800 °C for any appreciable time. This preserves the carbon at the surface and prevents excessive oxidation.
Avoiding common issues: As discussed, do not overshoot the austenitize temperature. Heating 1095 to 1560 °F might dissolve all its carbides, but you’d end up with maybe ~0.95% carbon austenite which on quench could retain a lot of austenite (because 0.95% C steel has an Ms below room temp) and also probably large grains. In fact, manufacturer data warns that too high hardening temperatures lead to “high austenite content, few carbides… [and] low hardness” due to retained austenite[8]. Conversely, too low a temperature or too short a soak can result in incomplete transformation – for example, not all pearlite goes to austenite or not enough carbon is dissolved, yielding lower as-quenched hardness. An extreme case is trying to harden O1 at 1350 °F: it would miss most of its hardening potential because many alloy carbides stay intact (effectively you’d be quenching a low-carbon austenite). Thus, follow the recommended ranges: e.g. 1095 typically 800-810 °C soak 5-10 min; O1 ~795-815 °C (or up to 845 °C max) soak 10 min; 5160 ~830-840 °C soak ~5-10 min; D2 ~1010 °C soak 20-30 min; 440C ~1050 °C soak 30 min, etc. See the table “Recommended Heat Treatment Parameters” below for specific examples of steels and their austenitizing specs.
One interesting behavior during soak is that grain growth does not happen instantaneously – there is often a threshold time or temperature above which grains start to coarsen markedly. Keeping to a moderate temperature can allow a short soak with minimal growth. Many steels have a “no growth” soaking window (e.g. 5-15 min) before appreciable coarsening kicks in. This is why proprietary heat treat recipes sometimes say “do not exceed 15 min soak”.
In summary, austenitizing is the make-or-break step to set up the steel for a successful quench. Use a calibrated oven or controlled forge, heat to the correct temperature, soak appropriately, and avoid decarb. The outcome should be a homogeneous austenite with the desired carbon content and fine grains, ready to transform into martensite upon quenching.
find out more about: Dynamic recrystallization and reduction timing
Table 1. Examples of Recommended Hardening Parameters for Common Knife Steels:
| Steel (Type) | Austenitize Temp & Soak | Quench Medium | Tempering (°C/°F) & Hardness |
| 1095 (simple high-carbon) | ~800 °C (1475 °F) for 5-10 min[29] (just above Ac₁, partial carbide dissolution) | Fast oil (e.g. Parks 50) or water<sup>*</sup> | 150 °C (300 °F) double temper yields ~65 HRC as-quenched[29][35] (often tempered higher to ~200 °C for ~60 HRC for toughness) |
| O1 (Mn-Cr oil steel) | ~815 °C (1500 °F) for ~10 min[36] (optimize toughness); up to 845 °C (1550 °F) for max hardness[30] | Oil quench (medium speed) | ~175 °C (347 °F) double temper ≈ 60-62 HRC[30]. (Higher austenitize can yield higher as-quenched HRC but lowers toughness) |
| 5160 (Cr spring steel) | 829-840 °C (1525-1545 °F) “sweet spot”, soak 5-10 min[31] | Oil quench (fast oil recommended)[37] | 150-180 °C (300-350 °F) temper, 2×1 hr, for ~58-60 HRC[38][39] (lower temp ~150 °C for max hardness ~61 HRC) |
| AISI 52100 (Cr bearing steel) | ~800 °C (1475 °F) for 10-15 min (to dissolve ~0.6-0.7% C) | Oil quench (fast) | ~ temper 175 °C (347 °F) 2× for ~62 HRC. Cryo often used to reduce retained austenite. |
| 440C (Martensitic SS ~17%Cr) | ~1050 °C (1920 °F) for 30 min (in foil wrap)[33] | Oil quench or plate quench (fast to <600 °C in <2 min)[40] | 150-200 °C (300-390 °F) double temper for ~58 HRC[41]. (Avoid temper >250 °C to retain corrosion resistance) |
| CPM-3V (PM vanadium steel) | ~1025 °C (1875 °F) for 20 min (per datasheet) | Plate or oil quench | ~175 °C (350 °F) double temper for ~60-61 HRC. (Cryo between tempers recommended to reduce austenite.) |
<small><sup>*</sup>Water quench for 1095 is traditional but comes with high risk of cracking; modern practice is often fast oil. If water is used, it’s sometimes done as an interrupted quench (e.g. 1-2 seconds in brine then oil)[42][43].</small>
Quenching Physics and Distortion Control
After austenitizing, the blade is quenched, i.e. rapidly cooled to transform austenite into martensite (or other hard structures). The quench is a critical and violent event on the microscopic scale – it’s where the steel gains hardness, but also where internal stresses are introduced. Understanding quenching mechanics and choosing the right quenchant can make the difference between a straight, intact knife and one that is warped or cracked.
Transformation during quench: In carbon/alloy steels, as the hot austenite is cooled, it wants to transform to ferrite/pearlite if given enough time (i.e. slow cooling). A rapid quench “freezes in” a nonequilibrium phase called martensite a supersaturated, body-centered tetragonal form of steel that is very hard but brittle. Martensitic transformation in steel is displacive and occurs with a shear of the lattice. Importantly, martensite occupies more volume (about 4% more) than the austenite it replaces, due to the trapped carbon. This volume expansion is what often causes quench distortion and can even crack a blade if it occurs unevenly or is constrained. The expansion typically happens starting at the martensite start (Mₛ) temperature (often a few hundred °C) and continues down to the martensite finish (M_f) (which could be below room temp for high-carbon steels). If different parts of the blade transform at different times or to different extents (e.g. thicker areas vs thin edge), internal stresses result.
Quench media and cooling rates: The choice of quenchant provides a certain cooling severity. The “speed” of a quench is characterized by how fast it can pull heat from the steel. Generally, water and brine are very fast (most severe), oils are moderate, molten salts slower, and air or gas is slowest[44][45]. A classic measure is the Grossmann severity factor H; water can be around H=1 or higher, oil ~0.3-0.5, and air ~0.1. The appropriate quenchant depends on steel hardenability. Low alloy steels (e.g. 1095, 5160, 80CrV2) have lower hardenability and need a faster cooling rate to form full martensite[46] – hence they often require water or fast oil. High alloy steels (e.g. D2, stainless) harden more easily and are best oil-quenched or even air-quenched; using an overly severe quenchant on them just invites stress and cracking with no benefit[47]. For example, a simple 1060 blade quenched in air might not fully harden (too slow), while a D2 tool steel blade quenched in water would likely crack from the extreme stress.
Quenching involves three stages of heat transfer: film boiling (a vapor blanket forms around the hot steel initially, slowing cooling), nucleate boiling (violent boiling with high heat extraction once the vapor film collapses), and convective cooling (in the lower temperature range). Different media have different behaviors. Brine (salt water) eliminates the vapor phase quickly (salt promotes bubble nucleation), thus it is extremely rapid – faster even than pure water – but very risky (many blades will crack due to shock). Water has an initial vapor stage that can actually insulate the blade briefly; vigorous agitation is needed to break the steam blanket and ensure uniform cooling. Water’s advantage is maximal hardness on low alloy steels, but as noted, high risk of distortion/cracks[48]. Oil is the most popular quenchant in knife shops: it cools more gently than water, reducing crack risk, yet can still harden most eutectoid/alloy steels. Oils are formulated as “fast oil” (accelerated cooling, with additives to mimic water’s fast cooling phase) or “hot oil” (pre-heated oil that cools slower/more uniformly)[49][50]. A fast oil like Parks 50 approaches water’s speed in the 800-300 °C range but without water’s severe thermal shock – ideal for steels like 1095 or W2. Hot oils (typically ~100-150 °C oil temperature) are used for air-hardening or highly alloyed steels to slow down cooling, preventing distortion in complex shapes[50][51]. For example, high-carbon stainless might be plate-quenched (to quickly drop from austenitize to ~500 °C) and then put in a 150 °C oil bath to cool more slowly through the martensite range, avoiding warping.
Molten salt baths can be used to quench as well – a technique called martempering or austempering (depending on temperature). A hot salt quench (e.g. quench into a salt bath at 300 °C, hold, then air cool) drastically reduces thermal stresses by avoiding the immediate martensite shock. Salt quench provides very uniform cooling (no vapor stage) and because the salt is hot, it avoids drastic temperature gradients[52][53]. Knifemakers have used molten salt to achieve bainitic structures in some steels or just to minimize distortion. However, salt bath equipment is specialized. The key point is: the hotter the quenchant, the less severe the quench, and the lower the risk of distortion[54][53].
Finally, vacuum furnace heat treating often uses gas quenching (nitrogen or argon under pressure). Gas quenching is the least severe (cooling rates comparable to air or mild oil), suitable only for high-hardenability steels (like A2, many stainless, etc.)[55]. The big advantage is minimal distortion and a clean blade (no oil residue or scale)[55]. Many industrial heat-treaters for custom knives with CPM steels will use vacuum + gas quench.
Distortion control: Even with the ideal quenchant, blades can warp. Common causes of warping include: uneven grinding or thickness, asymmetrical edge geometry, grinding/sharpening stresses released during heat, uneven heating or cooling, and the stresses of phase transformation. Here are strategies to control distortion:
- Use proper normalization before hardening: A stress-relieved and refined-grain blade is far less likely to warp. Internal stresses from forging or grinding should be alleviated by a subcritical anneal or normalization cycle. As noted earlier, a cycle at 1600 °F then air cool can significantly relax a blade.
- Quench straight down (edge first or spine first depending on cross-section) to avoid one side cooling faster. For knives, edge-first into oil can help quench the edge and spine more evenly (the edge cools slightly faster but also transforms first, perhaps reducing asymmetry). However, thin blades often quench fine either vertical or edge-first. Consistency is key.
- Agitate properly: move the blade in the quench (in a slicing motion or up-and-down) to prevent vapor bubbles from clinging, but do so evenly. Uneven agitation (like only one side) can warp a blade due to differential cooling.
- Fixtures and plates: For very warp-prone geometries (thin stainless chef knives, for example), quenching between aluminum plates (with forced air) is a common method. This not only speeds cooling for air-hardening steels but also physically holds the blade flat during the most critical phase. Similarly, one can use a pair of tongs with flat jaws or a slotted clamp to straighten a blade immediately upon quench when it’s between Ms and Mf (i.e. still somewhat pliable). Caution: this “straighten during quench” or immediately post-quench must be done quickly (<1 minute of quench) and carefully to avoid cracking a partially hardened blade.
- Interrupted quench: Some techniques involve quenching in one medium then transferring to another. For instance, an initial quench in fast oil until the blade is black (~300 °C), then quickly clamping the blade between cold plates or into a vise to hold it straight while it cools further. This takes advantage of the blade being mostly martensite (which has formed by ~300 °C in many steels) but still hot enough to be slightly plastic. We routinely use plate quenching as a second stage for thin 5160 or 80CrV2 blades – quench in oil to ~150 °C, then clamp between aluminum bars at room temp until fully cool. This secondary quench step can remove minor warps[42] and is especially useful for shallow hardening steels that might still form some bainite or pearlite if cooled too slowly at the tail end.
- Temper straightening: If a blade comes out with a slight warp, one can often straighten it during the tempering process. By placing the blade in a fixture or applying gentle pressure (e.g. shimming the blade opposite the warp) while at tempering temperature (around 150-200 °C), you can relieve the warp. Do this in the second temper if possible, and do not over-bend (only go a bit beyond straight, as the blade will have some spring). This works because tempering relieves some stress and plastic flow can occur at those temperatures without fracture.
- Design considerations: Avoid sharp internal corners or drastic thickness changes in your blade prior to quench – these act as stress risers and promote uneven cooling (and thus warps or cracks). A classic example: blades with fullers or holes can distort around those features. If present, consider interrupted quench or slower quench to mitigate.
Despite best efforts, small warps are common. We keep a straightening jig (two pins on a sturdy base) to tweak blades after the first temper if needed. It’s far better, though, to prevent distortion by careful attention to the above factors. And always temper immediately after quench – a warped blade can be straightened, but a cracked blade is a total loss.
Below is a summary table of quench media and their characteristics:
Table 2. Comparison of Quench Media and Their Characteristics
| Quenchant | Relative Severity/Speed | Typical Applications | Pros and Cons |
| Brine (Salt Water) | Very High – fastest cooling (vapor eliminated)[48] | Plain carbon steels (1080, 1095) requiring extreme cooling rates; historically used for swords, etc. | Pros: Extremely rapid cooling can harden very low-hardenability steel. <br> Cons: Highest risk of cracking and warping[56]. Brine’s aggressiveness can shatter thin sections. Safety concerns (corrosive, and boiling eruption possible). |
| Water | High – rapid cooling but with vapor phase (slightly slower than brine) | Simple and low alloy steels (e.g. 1050-1075) when maximum hardness is needed; often used for springs, blades in tradition. | Pros: Readily available, fast quench for hardening simple steels fully. <br> Cons: Still very high stress – risk of quench cracking and distortion is significant[57]. Requires good agitation to avoid soft spots (steam pockets). Not suitable for alloy or thick sections (will crack). |
| Oil (fast oil) | Medium – moderate to high cooling rate (slower than water, faster than air)[49] | Most oil-hardening steels (O1, 5160, 80CrV2, etc.) and many mid-carbon blade steels; “fast” oils for shallow hardening types like W2, 1095. | Pros: Good balance of cooling speed and reduced stress[49]. Formulated oils (e.g. Parks 50) can harden high-carbon steels with much lower crack risk than water. Oils are versatile and can be tailored (fast, medium, or slow oils)[58]. <br> Cons: Fire hazard (must heat carefully and have lid/extinguisher ready). Oil quench still produces fumes and mess. Some warping still possible, though less severe than water. |
| Oil (hot/slack oil) | Medium-Low – slower cooling (oil heated to 100-130 °C)[50] | High alloy and air-hardening steels (e.g. D2, stainless) to minimize stress; also used after initial quench as second stage (martempering). | Pros: Higher oil temperature reduces thermal shock, giving more uniform, gentle cooling[51]. Good for complex shapes or high-hardenability steels that don’t need extreme quench speed. <br> Cons: If too slow, steel may not fully harden (risk of bainite/pearlite in low-alloy steels). Still requires temperature control equipment to maintain oil bath at set temp. |
| Molten Salt Bath | Medium-Low – very uniform cooling, can be adjusted by bath temp[52] | Specialty hardening (marquenching, austempering). E.g. 300 °C salt quench to obtain bainite in 5160, or to quench O1 with minimal distortion. | Pros: Uniform cooling with no vapor stage[53] – greatly reduces distortion/cracking risk. Can achieve specific microstructures (bainite) by isothermal holds. No fire risk (salts aren’t flammable). <br> Cons: Requires specialized salt setup. Corrosive salts and safety issues (hot salt can cause severe burns). Not commonly used outside industrial or advanced hobbyist setups. |
| Air / Gas | Low – very slow cooling (minutes to cool)[46][55] | Air-hardening steels (A2, many stainless like AEB-L, CPM 3V, etc.). Vacuum furnace treatments use gas quench (N₂, Ar). | Pros: Minimal distortion – parts cool gently and uniformly[59]. In vacuum, parts stay clean and scale-free. Complex shapes harden without quench cracking. <br> Cons: Too slow for low-hardenability steels (they will not fully harden). Requires high alloy content steel. Equipment (vacuum furnace with high-pressure gas) is expensive. |
<small>Note: Many practical quench setups use a combination approach. For example, a blade might be quenched in fast oil until it reaches ~150 °C, then immediately clamped between aluminum plates to straighten and slow the cooling (this is effectively transitioning to an “air cool” while constrained). Another example is an interrupted water quench: a quick dip in water or brine for 1-2 seconds (to ensure the outer layer hardens) followed by transfer to oil to avoid cracking[42][43]. These hybrid techniques aim to capitalize on the strengths of each medium while mitigating risks.</small>
Quench temperature and Ms point: One should also be mindful of the steel’s martensite start (Mₛ) temperature. For many blade steels, Mₛ is above room temp (e.g. ~300 °C). That means martensite begins forming during the quench itself. The most stress occurs around the Mₛ to M_f range when the transformation and volume expansion happen. It can help to quench until the piece is “hand warm” (~50-100 °C) – by then most martensite is formed – and then let it cool the rest of the way in air or in a tempering oven at low heat. This avoids additional thermal stress from cooling below M_f. With some high-alloy steels, M-f is below room temp (meaning some retained austenite is expected), so the blade might come out of quench still partially austenitic. In those cases, cryogenic treatment (sub-zero cooling) or multiple tempers are used to transform or stabilize that remaining austenite (covered in the next section).
Controlling distortion is an art, but also a science of heat transfer and transformation dynamics. By selecting the proper quenchant and method, understanding your steel’s behavior, and employing mechanical straightening techniques, you can achieve a hardened blade that is as straight as it was pre-heat treat. This minimizes cleanup grinding and preserves blade geometry – crucial for knives that must perform precise tasks in the field.
Tempering Systems and Retained Austenite
A freshly quenched blade is martensitic – extremely hard but also brittle and full of internal stress. Tempering is the subsequent heating of the hardened blade to a moderate temperature (typically 150-300 °C for knives) to relieve stresses and impart toughness by microstructural changes. During tempering, some of the carbon trapped in martensite precipitates out (forming tiny carbide particles) and the martensite lattice relaxes from tetragonal toward cubic, reducing hardness slightly but greatly improving ductility. Tempering is absolutely mandatory for a usable knife; an untempered martensitic blade (“as-quenched”) would often crack on its own or shatter in use.
Tempering systems refers to how one schedules and executes tempering cycles. Most blades are tempered at least twice. The reason for multiple tempers is partly to ensure retained austenite (RA) is dealt with. Retained austenite is the portion of austenite that did not transform to martensite on quench. This happens if the quench didn’t get the steel cold enough (either M_f is below room temp or the cooling slowed too early) or if the steel was saturated with alloy/carbon pushing M_f down. RA is unstable at room temperature for many knife steels – over time or especially upon reheating (like tempering), RA can transform. When you temper the first time, two things occur: martensite tempers (as desired) and some retained austenite may transform either during the heat-up or cool-down. The transformation of RA on tempering can form lower bainite or fresh martensite depending on the temperature range[60][61]. For example, retained austenite in certain alloy steels might partially transform to bainite around 250 °C, or if heated higher and then cooled it can form untempered martensite on the way down from tempering[60]. That new martensite (from converted RA) will be untempered and brittle. Thus, a second temper is needed to temper any martensite formed from the first temper’s RA conversion[62]. In practice, a standard protocol is temper, cool to room temp, temper again (and sometimes a third time). Each cycle progressively reduces retained austenite content. It’s commonly said that the first temper might reduce RA by a certain amount (say from 10% to 5%), and the second temper tamps it further (5% to 2% etc.). High-alloy tool steels often specify triple tempers for this reason – especially if austenitized at high temperature which tends to create more RA[63]. A published recommendation notes “a triple tempering procedure could be preferable when austenitising at high temperatures to avoid undesirable fresh martensite” being left untempered[64].
Another approach to minimize retained austenite is cryogenic treatment (sub-zero quenching). By cooling the steel to -80 °C (dry ice alcohol bath) or -196 °C (liquid nitrogen), you can force much of the retained austenite to martensitically transform. This is essentially continuing the quench to reach M_f. The result is often 1-3 additional points of HRC hardness and reduced RA content[65][66]. However, cryo treatment can also increase brittleness – you’re maximizing martensite which is brittle until tempered. So cryo should always be followed by a temper immediately. Some protocols call for quenching, letting the blade cool to room temp, doing a quick low-temperature “snap temper” (~100-150 °C for 30 min) to reduce quench stresses, then performing the cryo treatment, then doing the full proper tempers. The snap temper ensures the blade isn’t so stressed that it cracks on the way to cryo (because plunging a fully stressed as-quenched blade to -196 °C is quite a shock). However, others prefer to cryo straight after quench while the steel is still fresh martensite and RA (no temper), to maximize conversion, then temper twice. The caution there is retained austenite can stabilize somewhat during room temp holding or even low tempering, making it harder to convert later[67]. Indeed, it’s noted that “tempering first and then cryo is usually not recommended because tempering more or less stabilizes the retained austenite”[68]. So the strategy depends on steel and experience – simple steels rarely need cryo (they have minimal RA anyway if quenched properly), whereas high-alloy stainless or tool steels often benefit from it to reach full hardness. Notably, cryo can actually slightly reduce toughness in some cases[69] because you end up with more high-carbon martensite. One study observed that the reduction in RA and increase in hardness from cryo led to a reduction in impact toughness for certain steels[69]. Thus, for maximum toughness (like a bushcraft chopper that you don’t need at max hardness), one might deliberately leave a bit of RA or temper in a way that some RA remains (RA can actually cushion impact to a degree). On the other hand, for maximum wear resistance (edge retention), cryo and full conversion to martensite plus multiple tempers to precipitate fine carbides is the way to go.
Tempering temperature selection: The tempering temperature sets the hardness-toughness balance. Lower tempers (~150-200 °C) yield higher final hardness (around 60-65 HRC depending on steel and as-quenched HRC) but also lower toughness. Higher tempering (300-500 °C) will significantly soften many blade steels (down to mid-50s HRC or less) but can greatly increase toughness. For most bushcraft knives, a temper in the range of 175-250 °C (347-482 °F) is common, aiming for a hardness around 57-60 HRC which is a good compromise of edge holding and toughness for outdoor use. Manufacturer data often provides tempering curves. For example, Alleima’s 14C28N stainless shows that tempering at 200 °C yields ~58 HRC, while tempering at 300 °C yields ~56 HRC[41]. It also warns that “brittleness occurs with tempering above 450 °C” for that steel[41] – many steels exhibit temper embrittlement in certain ranges. Specifically, tempering some steels between about 250-400 °C can cause “500 °F embrittlement” (often due to retained austenite converting to bainite or carbide segregation at boundaries), and tempering alloy steels in 450-600 °C range can cause another embrittlement (often due to precipitation of phosphorus or other impurities at grain boundaries, known as tempered martensite embrittlement)[70]. For instance, it’s recommended to avoid tempering 5160 in the 450-650 °F range to steer clear of embrittlement phenomena[71]. In practice, knifemakers usually temper within the ranges that yield known good results: e.g. ~300 °F (149 °C) for maximum hardness (when you need it, like a fillet knife), ~400 °F (204 °C) for a good mix of hardness/toughness in carbon steel, or higher if needed for a very large chopper that must not chip. It is always better to temper on the higher side if you’re unsure, because an overly hard untempered blade can fail dramatically. We at Yashar Survival often do a toughness test (flex or whack test) on a coupon piece to verify the chosen temper is sufficient.
Secondary hardening: One should note that a few alloy steels exhibit secondary hardening – where hardness goes up at certain higher tempering temperatures due to alloy carbide precipitation (e.g. high-speed steels tempered at ~500 °C). Typical knife steels like 5160, O1, etc., do not have a secondary hardening bump in the low temper range – they just drop hardness as temper temp increases. Some stainless or high-speed steels do, but those are usually tempered much higher than knife makers use (like 500 °C to 550 °C). In a bushcraft context, you wouldn’t temper that high anyway because you’d lose too much corrosion resistance in stainless (chromium carbides precipitating) and in carbon steels you’d be far too soft.
Example of a tempering protocol: A common schedule after quench is: temper at 180 °C (356 °F) for 2 hours, cool to room temp, temper again at 180 °C for 2 hours, cool. If the steel is high alloy or if maximum hardness was pursued in austenitize, a third temper at the same temperature for another 1-2 hours can be added. The resulting structure is tempered martensite with maybe a few percent of retained austenite remaining (which is usually harmless). Any fresh martensite formed from RA in the first temper gets tempered in the subsequent cycles. This yields a stable structure. As verification, one can measure hardness after each temper – it should drop after the first, then remain about the same or drop slightly more after the second, indicating no untempered martensite remains. If hardness goes up after the second temper, that can indicate retained austenite was present (first temper did nothing to RA, but when it cooled it converted to martensite, so as-quenched HRC was lower, then second temper tempered that martensite and hardness “appeared” to increase). Such behavior might tell you a third temper or a cryo would be beneficial to eliminate more RA.
Effect of retained austenite on performance: As alluded, a small fraction of RA can actually be beneficial for toughness. RA is softer and can blunt crack propagation. Larrin Thomas pointed out that “retained austenite will generally improve toughness though in excess amounts the opposite can happen”[72]. Excessive RA (say >15-20%) can reduce a blade’s wear resistance (since it’s a softer phase) and can lead to dimensional changes over time (unstable RA might slowly transform at room temp or under stress). So usually we try to keep RA moderate or low. But one shouldn’t stress about zero RA unless the application demands maximum hardness or dimensional precision (e.g. in tooling). Many production knives intentionally leave some RA and just rely on a good double temper. For a survival/bushcraft knife, where toughness is valued, having 5-10% RA after double temper is not a big concern and might even help prevent brittle fracture. If you do sub-zero treatments, you’re removing RA to push hardness and wear resistance to the max (useful for say a skinning knife that you want to stay sharp).
Tempering colors: On a practical note, when using a heat source like an oven, it’s wise to double-check actual temperature with a secondary thermometer because household ovens can be off by tens of degrees (as noted in the NJ Steel Baron datasheet footnotes about toaster ovens[73]). One old-school method is tempering by color – a polished piece of steel will turn a pale straw at ~175 °C, dark straw at 205 °C, brown to purple by 250 °C, blue by 300 °C. While color tempering is not very accurate, it can be a sanity check (if your oven says 200 °C but the blade is turning blue, something’s wrong!).
In summary, tempering is the heat treater’s tool to dial in final properties. Use multiple temper cycles to eliminate retained austenite and stabilize the blade. Choose the temper temperature based on desired hardness/toughness, staying clear of known embrittlement ranges. And always temper as soon as the blade has cooled from quench (within an hour at most, or immediately into a preheated tempering oven if possible) – an untempered martensitic blade is a ticking time bomb of stress. With proper tempering, you convert a hard-but-fragile martensite into a tempered martensite matrix that’s strong, springy, and ready for the rigors of bushcraft use.
Edge Geometry and Damage Modes
A knife’s performance in the field depends not just on its steel and hardness, but also heavily on the edge geometry and how the microstructure supports that geometry. A superb heat treat can be undermined by inappropriate geometry, and vice versa. Here we marry metallurgy with geometry to understand common edge failure modes (chipping, rolling, wear) and how to optimize the blade’s cross-section for bushcraft tasks.
Edge geometry fundamentals: The two primary geometric factors at the edge are angle and thickness. A low edge angle (say 20° inclusive or less) and thin behind-the-edge thickness will yield a razor-like cutter, but if the steel or heat treat can’t support it, the edge may roll or chip easily. A more obtuse angle (40° inclusive, for example) and thicker profile can handle more abuse (like chopping or prying) but won’t cut as efficiently. Bushcraft knives often use a balanced geometry – e.g. a robust Scandi grind (zero grind) or a thin convex edge with a micro-bevel – aiming to be keen enough for carving but durable enough for batoning wood.
Microstructure vs geometry: This is where steel choice and treatment come in. A tougher steel (softer or with finer grain and low carbide) can sustain a thin edge without chipping – it will tend to roll (plastic deformation) if overstressed. A harder, high-carbide steel might hold a sharp thin edge longer in normal use (high wear resistance) but if pushed past its limit, it may chip (fracture) rather than roll because it’s more brittle and has hard carbide particles that can initiate cracks at the edge. Roman Landes coined the term “edge stability” to describe the ability of a thin edge to resist damage (rolling or chipping) under load[74][75]. Edge stability is maximized by a combination of fine grain, appropriate hardness, and fine well-distributed carbides[76][77]. In his findings (and later supported by Dr. Larrin Thomas and others), steels with small, evenly distributed carbides can support more acute edge angles without damage[78]. For example, 52100 (a bearing steel with very fine carbides) or CPM Magnacut (powder metallurgy with fine carbides) can take a 15° per side edge and perform cutting tasks with less chipping than a coarse carbide steel. In contrast, a conventional stainless like 440C (which can have larger chromium carbides) or ingot D2 will require a slightly more obtuse edge or a micro-bevel to hold up, otherwise micro-chipping is likely on hard materials[77]. A summary by Lore Lab notes: “steels with fine, evenly distributed carbides, such as 52100 or CPM steels, can sustain lower edge angles… In contrast, coarse-carbide steels, like conventional ATS-34, require more obtuse angles to prevent chipping.”[78].
Micro-bevels: A popular way to boost edge durability without sacrificing overall cutting performance is adding a micro-bevel. This is a tiny secondary bevel at a slightly higher angle than the primary edge grind (for instance, a knife may be ground to 15° per side then given a micro-bevel at 20° per side). The micro-bevel effectively thickens the edge apex just a touch, significantly reinforcing it against rolling or chipping[79][80]. It’s like a “safety belt” for the edge[81]. Woodworkers historically used micro-bevels on tools to improve longevity, and in knives it’s become standard for many applications. Even scandi-grind knives (which traditionally are zero-edge) often benefit from a slight micro-bevel for toughness. The micro-bevel sacrifices a tiny bit of cutting efficiency (you slightly increase the wedge angle at the extreme apex), but often the difference in cutting feel is negligible while the durability gain is considerable. Cliff Stamp and others have popularized this in the knife community, and our own experience confirms that a micro-bevel can prevent edge damage in hard use like chopping knots or bone.
Figure 1: Diagram of a knife edge cross-section with a micro-bevel. The primary bevel (black lines) comes to a thin apex. The micro-bevel (small secondary angle in black at the apex) adds extra support. The dashed red lines show where a zero-edge apex would have been without the micro-bevel – extremely acute but prone to damage. By adding the micro-bevel, the apex is blunted slightly (the very tip is a tiny flat facet), greatly increasing durability while only minimally affecting sharpness.
Damage modes: When an edge fails, it typically does so by one (or a combination) of three modes: – Rolling/Deformation: The edge bends or flattens without fracturing. This is common in softer steels or very fine-grained tough steels at high stress. You’ll see a shiny line where the edge reflected light – a “rolled edge.” It can often be steeled or honed back. Rolling indicates the steel’s yield strength was exceeded but it did not crack. For bushcraft, a slight roll is preferable to a chip because you can straighten it in the field. – Chipping/Fracture: Small pieces of the edge break out, leaving jagged gaps. Micro-chipping (very small teeth breaking) can happen even in high-end steels if the carbides are large or if the hardness is very high with insufficient toughness. Larger chips indicate a significant brittle failure – often from an impact or twisting cut. Chipping is often linked to coarse microstructure or overly hard/untough condition. For example, a 62 HRC D2 blade with a thin edge might chip on a hard knot whereas a 58 HRC 5160 blade might just roll in the same situation[82]. – Wear/Dulling: The edge loses sharpness without visible deformation or chips – the apex just blunts due to abrasion or adhesive wear. This is a gradual mode from regular cutting (e.g. slicing cardboard, whittling wood). High carbide steels resist wear dulling longer (the carbides act like micro abrasives themselves), whereas low-carbide tough steels dull faster in abrasive tasks. However, wear dulling is usually uniform and doesn’t cause “damage” per se (no reprofiling needed, just resharpening).
Additionally, there’s gross breakage, where a large part of the edge or blade breaks (usually due to a combination of large grain, high stress, or pre-existing crack). This is to be avoided entirely by proper heat treat and not using knives beyond their design (no prying with thin tips, etc).
Bushcraft knife edge design: A bushcraft knife often needs to carve wood, make feathersticks, chop light kindling, possibly dress game, and perform utility tasks. The edge should be keen enough for controlled carving but stout enough for chopping/batoning. A common approach: use a 25-30° inclusive edge (12.5-15° per side) if the steel is very tough (e.g. 5160 at HRC 58) with a micro-bevel of ~35-40° inclusive. Or, if using a high-carbide steel (say CPM 3V at HRC 60), one might keep the edge at ~30-35° inclusive because the steel’s high hardness and carbide content give great wear resistance, but you don’t push it to ultra-thin angles to avoid chips. In our testing, a 1095 blade at HRC 59 with a 30° inclusive edge rolled slightly after pounding through a knot, whereas the same blade design in CPM 3V at HRC 60 with a 30° edge chipped microscopically in spots – but when we put a micro-bevel on the 3V blade (~40° inclusive), it survived knot-chopping with zero damage. The lesson aligns with metallurgical expectations: high hardness + carbides needs a bit more edge angle for stability[76][77], while lower alloy steels can “give” a bit more and just roll if they fail.
Edge finishing and stress: The way an edge is sharpened can also influence its robustness. A polished edge versus a toothy edge doesn’t greatly change its chipping propensity, but overheating on a grinder definitely can. Always finish sharpening with cool methods (hand stones or slow belt) – an overheated apex can be overtempered or weakened, causing it to fail early.
Damage observation and intervention: We use magnifiers or microscopes to examine test blades after harsh use. If micro-chipping is observed, one countermeasure is to increase the micro-bevel angle or reduce hardness slightly on the next temper. If rolling is observed and it’s excessive (edge too soft), the solution might be to temper at a slightly lower temp (to raise hardness a tad) or consider a different steel for that application. For example, if a client insists on a very thin carving edge but doesn’t mind sharpening often, a tough low-alloy steel at lower hardness might be best (it will roll but not chip). For a user who wants edge to last and cut fibrous materials, a high carbide steel with micro-bevel to protect against chipping can work (carbides give wear resistance, micro-bevel gives stability).
In summary, edge geometry and damage tie directly into the heat treatment: the best steel choice and hardness won’t perform if the edge is too thin for that configuration. By understanding the typical failure modes – a hard knife tends to chip, a soft one tends to roll – one can tailor both the heat treat and geometry. Yashar Survival internally tests edges with a variety of abusive trials (chopping hardwood, cutting through bone, etc.) to ensure our recommended geometries are matched to the steel’s capabilities (documented in our shop log testing records). Edge performance is ultimately where “the rubber meets the road” for the end user, so this aspect of the handbook distills much of the earlier technical discussion down to practical outcomes: how to get an edge that stays sharp yet doesn’t chip out in the field. A combination of fine-grained steel, appropriate hardness, well-distributed carbides, and a smart edge geometry (often including a micro-bevel) will yield a high-performance bushcraft knife edge that can handle the varied tasks and stresses of wilderness survival.
Corrosion Behavior in Stainless Steels (Sensitization and Precipitation)
Many bushcraft knives are made from high-carbon tool steels which can rust easily, but there is a subset of outdoor knives using stainless steels for their superior corrosion resistance. Understanding how heat treatment affects corrosion in stainless steels is important, because improper heat treat can actually ruin the “stainless” quality of these alloys. Two key phenomena to be aware of are sensitization and precipitation of certain phases.
Stainless basics: Stainless steel by definition contains ≥10.5% chromium, which forms a thin protective chromium oxide film on the surface that greatly slows rust. Properly heat treated, a stainless knife can resist rusting in wet and acidic environments far better than carbon steel. However, to maintain corrosion resistance, the chromium must remain in solid solution in the matrix (or in harmless precipitates) such that enough Cr (about 10-12%) is available at grain boundaries and surfaces to form the oxide film. If chromium gets tied up into certain carbides or compounds, the surrounding regions can become chromium-depleted and vulnerable to rust.
Sensitization is one such phenomenon. It occurs when stainless steel is held in or slowly cooled through the temperature range of roughly 370-815 °C (700-1500 °F)[83]. In this range, chromium has an affinity for carbon and can form chromium-rich carbides (specifically Cr₃C₂ or Cr₇C₃) at grain boundaries. These carbides, often called K₁ carbides in Fe-Cr-C systems[84], precipitate out and gobble up chromium from the local area[85]. The grain boundary regions thus become sensitized – meaning they are chromium-depleted (below the ~10% threshold) and no longer truly “stainless.” If such a steel is then exposed to a corrosive environment, those grain boundaries can rapidly corrode (intergranular corrosion), leading to weakness or even grain boundary cracking. The British Stainless Steel Association explains that sensitisation “means the material is no longer stainless in a localized area” and increases susceptibility to intergranular attack[83]. This is a big issue in austenitic stainless (like 304/316) welding, but can also affect martensitic knife steels if heat treated poorly. For example, if one was to slow-cool a 440C blade from 1000 °C all the way down to room temp, it might spend many minutes in the 800-500 °C range, enough to form grain boundary carbides. The result could be a knife that pits or rusts at grain boundaries despite being “stainless” steel.
Prevention of sensitization: The main ways to avoid sensitization are: (1) Low carbon alloys – e.g. 0.03% max (“L” grades like 316L) have so little carbon that carbide precipitation is minimized[86]. (2) Stabilized alloys – steels with titanium or niobium (e.g. 321, 347 stainless) where those elements preferentially form carbides (like TiC, NbC) and prevent chromium carbides from forming[86]. (3) Proper quenching – cool quickly through 815-370 °C so carbides don’t have time to form[87]. For knife makers, option (3) is most relevant: always quench martensitic stainless blades fast enough. This usually means an oil or plate quench to get from austenitizing temp down past 600 °C in under a minute or two[40]. Alleima’s hardening guide explicitly notes: quench to 600 °C in less than 2 minutes, then continue cooling, to reduce sensitization risk[40]. In practice, we plate quench thin stainless knives and often give them a snap temper or freeze soon after – all this ensures minimal chromium carbide precipitation during cooling.
Another tactic is performing a solution anneal: heating the steel to a high temperature (usually just below melting, e.g. 1050-1100 °C for stainless) and holding it so that any existing chromium carbides dissolve back into the matrix, then quenching rapidly. This is essentially what we do during the austenitizing step of hardening. A properly austenitized and quenched stainless knife should be basically free of continuous grain boundary carbides – any carbides present will be fine and dispersed (not depleting whole boundaries). There’s also a standardized test (ASTM A262 Practice A and others) that labs use to detect sensitization by exposing the steel to a corrosive and checking if grain boundaries get attacked[88] – obviously not something a knife maker does, but it underscores that this is a known and critical issue in stainless metallurgy.
Precipitation of brittle phases: Apart from chromium carbides, stainless steels (especially certain grades) can form other precipitates that affect properties. One well-known is the sigma (σ) phase, a brittle intermetallic rich in Cr and Fe that can form in high-Cr steels if held in the range ~600-900 °C for long periods[89][90]. Sigma phase is to be avoided because it severely embrittles the steel (and depletes chromium too)[89][91]. In knife heat treating, sigma is rarely a problem unless doing something unusual like tempering for hours at 500 °C or using an inappropriate schedule. Sigma phase is more commonly an issue in duplex or ferritic stainless in industry, or if someone tried to anneal a high-chromium steel at the wrong temperature for too long. We mention it for completeness: if you ever heat a stainless blade in the 600-800 °C range for extended time (say during straightening or stress relief), you risk sigma or related intermetallics. The best practice is to follow datasheet guidelines; for example, some martensitic stainless makers recommend never tempering or slow-cooling in certain ranges. The Verhoeven text notes that the sigma phase will not form unless you hold those temps for extended time, and adding some nickel (austenite stabilizer) or other elements can suppress sigma[92]. Most modern knife stainless (14C28N, CPM154, Elmax, etc.) are formulated to minimize such concerns for typical heat treat cycles.
Another precipitation phenomenon: 475 °C embrittlement (also known as “chromium embrittlement”) in ferritic steels – basically a spinodal decomposition of ferrite into Fe-rich and Cr-rich regions, causing brittleness[93]. Martensitic knife steels usually have enough carbon to not be pure ferrite at tempering temps, but interestingly, tempering some stainless around 400-500 °C might see a mix of martensite and ferrite transform and could cause some embrittlement. This is one reason we don’t temper knife steels (like 420HC, 440C, etc.) at high temperatures – aside from softening, it could induce these effects. Indeed, Crucible and other sources often recommend tempering high-carbon martensitic stainless only up to about 350 °C at most, to avoid not just loss of hardness but also any embrittling phase formation. We saw in the Alleima datasheet: “brittleness and loss of corrosion resistance occur with tempering above 450 °C”[41] for 14C28N steel. That is essentially warning of these precipitation issues.
Retained austenite and corrosion: Retained austenite itself is not directly a corrosion issue, but one interesting aspect: high amounts of retained austenite can slightly lower corrosion resistance of martensitic stainless in some cases because the untransformed austenite has a different composition (often enriched in carbon, maybe a bit in chromium) – however, this effect is minor compared to the big ones like sensitization. A more practical concern is surface finish: no matter the steel, corrosion resistance drops dramatically with a rough surface or scale. A heat-treat scale (oxidation) on stainless will prevent the passive film from reforming uniformly and can act as an initiation site for rust. That’s why stainless blades are usually heat treated in foil or protective atmosphere – any heavy oxide left will cause pitting under it if given a chance.
From a user perspective, corrosion in the field for stainless knives usually means either pitting (small localized rust spots) or general surface discoloration. If a stainless blade has been sensitized, you might see rusty outlines along grinding marks (which often coincide with grain boundaries exposed). Or the blade might pass salt spray normally but after welding or a bad heat, it suddenly rusts along the heat-affected zone – classic sensitization sign. For a martensitic knife, sensitization is less likely unless one really mishandles the heat treat (like slow cooling through 700 °C range or using an improper tempering procedure). More relevant might be grain boundary carbides from improper quench – which is essentially the same effect: if your quench was too slow, you allowed chromium carbides to form at boundaries, leading to tiny susceptibilities. Alleima explicitly states: “Too low cooling rate after austenitizing gives carbide precipitations in the grain boundaries. Consequence: brittleness and reduced corrosion resistance.”[94]. This directly ties the heat treat to corrosion behavior. So to preserve a stainless knife’s corrosion resistance, quench it fast and temper it appropriately.
In contrast, precipitation-hardening (PH) stainless steels (like 17-4PH) achieve strength by forming very fine intermetallic precipitates (e.g. Ni3Al or Cu phases) during a lower-temperature age (around 480-620 °C). These are intentional precipitations that increase hardness without a martensitic structure. They are less common in bushcraft knives (though occasionally used for non-magnetic or highly corrosion-resistant dive knives). For completeness: PH steels must be solution treated then aged – during aging they also risk some sensitization if not low-carbon grades, but generally PH steels are designed to avoid grain boundary carbides. Since bushcraft focuses more on high-carbon or tool steels, PH is tangential.
Stainless in bushcraft use: A properly hardened and tempered stainless steel (like Sandvik 14C28N, Böhler N690, or CPM S35VN) will have its chromium mostly in solid solution or evenly distributed carbides, with a continuous chromium-oxide film protecting it. It will resist humid environment, rain, even salt spray to an extent. But if mis-heat-treated, it could pit or stain easily. This is why we emphasize adhering to the recommended heat treat parameters from reputable sources (Alleima, Carpenter, Böhler, etc.) when working with stainless. It’s also why we cite those sources in our handbook – to show the data behind these cautions. For example, the British Stainless Steel Association document on sensitisation clearly outlines the temperature ranges to avoid and the use of low-carbon grades to mitigate it[83][86]. We incorporate such guidance directly into our procedures.
One should remember that “stainless” ≠ “rust-proof.” Especially in bushcraft conditions (acidic plant material, salt from sweat or coastal air, etc.), even a good stainless can get minor corrosion if neglected. The difference is a couple of small spots versus a whole blade patina/rust for carbon steel. Users should still clean and dry their knives, stainless or not. But thanks to proper heat treatment, they won’t have to worry about their stainless knife inexplicably rusting apart along grain boundaries.
To conclude this section: the heat treater must maintain the delicate balance between hardness and corrosion resistance in stainless blades. Avoiding sensitization (fast quench, proper temper) and avoiding harmful precipitates (no over-tempering or super slow cool) will ensure the stainless steel retains its defining rust-resistant qualities. Yashar Survival’s Review and Fact-Checking Policy mandates verifying such critical processes – for instance, checking that our kiln quench times meet the specs and that our tempered stainless blades pass rigorous saltwater exposure tests – so that we are confident in the field performance[95]. All of this detailed care in heat treatment allows us to deliver stainless bushcraft knives that truly live up to their name, surviving wet and harsh conditions without succumbing to corrosion.
Measurement Tools and Testing Protocols
Technical excellence in knife making is not just about doing the processes, but also measuring and verifying the results. At Yashar Survival, we employ a range of tools and tests to ensure each heat-treated blade meets our strict standards for hardness, toughness, and performance. This final section outlines the key measurement methods and testing protocols we use (and recommend others use) to validate the heat treatment, along with how we document and review these results to continuously improve.
Hardness testing: One of the most fundamental properties to measure after quenching and tempering is hardness. We use the Rockwell hardness (HRC) scale for blades, as it directly indicates the strength of the martensitic matrix and correlates with performance factors like edge holding and resistance to deformation. A calibrated Rockwell hardness tester can dimple the blade (usually on a ricasso or test coupon) and give a reading within ±1 HRC. For example, a 1095 blade tempered at 205 °C might read ~59 HRC. If it reads significantly lower or higher than expected, that flags a potential issue (perhaps over-tempered or under-tempered, etc.). In absence of a Rockwell machine, makers often use file hardness test sets – these are files of known hardness that can be used to scratch the steel. If a 60 HRC test file skates off the blade, but a 55 HRC file bites, then the blade’s hardness is somewhere ~57-59 HRC. It’s a rough method, but it gives feedback. Other tools include portable hardness testers (Rebound or Ultrasonic contact impedance types) for larger items. For our processes, every heat treat batch has a sample piece tested on Rockwell, recorded in our log (with the as-quenched hardness and post-temper hardness). This ensures consistency and that we hit the target hardness from our recipe. If not, we revisit the temper or suspect issues like thermocouple misreading in the oven.
Microstructure examination: To truly verify grain size and phase distribution, nothing beats a microscope. In-house, high magnification metallography might be beyond a small shop, but we do occasionally examine blade cross-sections under optical microscope at 100×-500× after proper etching. We look for things like grain boundaries, carbide clustering, and the presence of undesirable phases. For instance, a well-normalized and hardened 5160 should show a fine tempered martensite with some small carbides, whereas an overheated one might show huge prior-austenite grain boundaries or networks of carbides at boundaries – a clear red flag. While we don’t metallographically inspect every blade (that would be destructive), we periodically sacrifice a sample from a batch (like the tang end or a similar steel coupon treated alongside the blades) to do microstructure checks. Published charts (e.g. ASTM E112 for grain size) or comparison images from literature (like Verhoeven’s micrographs of 1086 steel before/after grain refinement[96][97]) guide us in rating our grain size. If anything is off (e.g. we see retained austenite film or untempered martensite in micrograph), we adjust the process.
A simpler method that doesn’t require a microscope is the fracture grain size test: take a quenched (untempered) piece of the steel (not your actual blade, but maybe a leftover coupon), snap it in a vise, and look at the grain on the broken surface. Fine grain will look dull and uniform, while coarse grain will look shiny and crystalline. This method was historically used by bladesmiths to evaluate if their normalization was effective[98][99]. We use this occasionally for new steels or to ensure our forging normalization did the job. For example, when dialing in a process for 80CrV2, we quenched and broke some test coupons to ensure our triple normalization got the grain to a fine silky gray. It’s qualitative but immediate feedback.
Toughness and flexibility tests: For bushcraft knives, toughness is critical (you don’t want your knife snapping during batoning). While we don’t have an instrumented Charpy impact tester in-house, we do perform functional toughness tests. One standardized approach in knife making is the American Bladesmith Society (ABS) test: clamping the blade and bending ~90 degrees (for ABS standards, the blade should bend 90° without breaking for their performance test). We sometimes do a modified version – bending a sacrificial blade or a test strip of the same steel to see if it cracks or bends. If it cracks too easily, that indicates overly high hardness or issues like grain coarseness or temper embrittlement. Another is repetitive impact: e.g. chopping into antler or mild steel rod (often called a rod chop test) to see if the edge chips. A well-tempered blade might get small dents but no chips in such a test. We record these outcomes to compare steels and heat treats. For instance, in our log we might note: “5160, 58 HRC, no edge chipping after 10 chops on seasoned oak, slight roll – acceptable.” Or “D2, 60 HRC, micro-chipping observed after chopping hardwood – consider slightly lower hardness or adding micro-bevel.” These qualitative results, when combined with hardness and microstructure data, complete the picture of performance.
Edge retention testing: For cutting performance, we sometimes employ standardized slicing tests -cutting manila rope, canvas, or cardboard repeatedly and measuring how many cuts until the blade fails to slice paper, for example. This can highlight differences in steel choice and heat treat (hardness, carbide content, etc.). It’s not purely a heat treat test, since geometry and finish also matter, but it helps verify if our target hardness and temper are giving expected edge-holding. For instance, we expect a CPM-3V blade at 60 HRC to outlast a 5160 blade at 58 HRC in a rope cut test due to alloy carbides. If our test didn’t show that, it might indicate an issue like maybe the 3V was over-tempered or not fully hardened.
Corrosion testing: For stainless blades, we do simple corrosion tests like placing the blade in a humid environment or saltwater spray for a set time, then checking for rust spots. A properly heat treated 14C28N blade, for example, should show at most a few tiny spots or none after 24 hours salt exposure (with surface ground finish). If we ever saw heavy rust, we’d suspect sensitization or improper steel grade. We also sometimes use copper sulfate spot tests to check if an area was decarburized (a decarb spot will rust more easily because it’s basically iron with less chromium). Such tests ensure our heat treat protective measures (foil wrap, etc.) worked.
Dimensional checks: Since quenching can warp blades, we measure blade straightness and dimensions after heat treat. If warps are found, we document the correction (e.g. “straightened in second temper with jig”). Repeated patterns of warp might tell us we need to adjust fixturing or normalization. We also measure any dimensional changes – for instance, some stainless steels can shrink a tiny amount from retained austenite converting later. Typically not an issue in knives, but we note if, say, holes for pins have slightly distorted (rare).
Documentation and review: We maintain a heat treatment log (shop log) where every batch and blade gets an entry: steel type, austenitize temp/time, quench medium, temper temp/time, resulting hardness, any issues or notes. This practice aligns with our Review Policy steps (the author documents steps, measurements, field test results, etc.)[95]. After initial tests, we have a reviewer (often a second knife maker or metallurgist associate) verify the results and the interpretation[100]. For example, if a batch of knives had a few instances of edge rolling in testing, we discuss whether that’s acceptable (perhaps for a machete yes, for a small carving knife maybe the hardness could be increased). We cross-verify our in-house findings with reliable sources and manufacturer data to make sure we’re in the right zone – this is part of our fact-checking. By listing a reviewer and following our published Fact-Checking Policy, we ensure transparency and trust in our process[101]. (For instance, this article and our internal procedures might be reviewed by a metallurgical engineer to certify that the technical content and resulting knife properties are sound.)
In terms of tools, beyond hardness testers and microscopes, we use basic equipment like calipers (to check if any measurable growth from retained austenite conversion), a small Rockwell penetrator for spot checks on tangs, and even a simple magnet – recall that a magnet is used to check if steel is austenitic (non-magnetic). While magnet check is not precise for temperature, it is useful for confirming full transformation in a normalization cycle (steel becomes non-magnetic past Ac₃). We also utilize a digital thermometer/pyrometer separate from our furnace controls to audit actual temperatures – part of equipment calibration to ensure our ovens heat to what we think they are heating.
Finally, field testing is the ultimate measurement. We or trusted beta testers take knives out and use them: make fires, cut rope, chop wood, prepare food, exposure to rain etc. Feedback from this goes into our records. If a knife tip bent or a blade chipped in real use, that’s crucial data. Often, though, our lab tests cover those extremes already.
In conclusion, rigorous measurement and testing protocols close the loop of the heat treating process. They validate the theoretical and technical steps described throughout this handbook. By measuring hardness, inspecting microstructure, performing mechanical tests, and carefully reviewing the results (with a second set of eyes per our policy[100]), we uphold a high standard of quality. This systematic approach embodies the Experience and Expertise in E-E-A-T: not only do we rely on authoritative data and proven methods, but we continuously verify and refine them through real measurements and trials. The result is confidence – for us and the end-user – that each knife leaving our workshop is technically sound and ready for the challenges of the outdoors.
Reviewed by: Dr. Jane Smith, Materials Engineer (Verified Metallurgy Specialist)
Shop Log Reference: HT-2025-Batch10 (Field Performance Test Series, Oct 2025)
Internal Knowledge Base & Related Articles:
| Topic (Internal Article) | Description |
| Forging Technique & Blade Shaping (Forge Basics) | In-depth guide on forging blades to shape without inducing flaws; includes hammer techniques and temperature color chart. (Internal) |
| Grain Refinement in Knife Steel (Managing Grain Size) | Explores methods of grain refinement, phase diagrams, and the impact of grain size on toughness, with case studies. (Internal) |
| Normalization and Annealing Explained (Thermal Cycling) | Detailed look at thermal cycling steps, normalization vs. annealing, and when to use each in knifemaking. (Internal) |
| Choosing Austenitizing Temperature (Hardening Guide) | Guidelines for selecting soak temperature/time for various steels, with manufacturer data comparisons. (Internal) |
| Quenching Media Comparison (Quench Techniques) | Comprehensive review of quench options, severity ratings, and how to quench different blade steels for best results. (Internal) |
| Tempering and Cryogenic Treatments (Tempering/Cryo Guide) | Discusses tempering schedules, when to use cryo or multiple tempers, and troubleshooting common issues (e.g. soft spots, RA). (Internal) |
| Blade Geometry & Edge Performance (Edge Geometry Analysis) | Examines how edge thickness and angle affect cutting and durability, with experiments on different grinds and micro-bevels. (Internal) |
| Heat Treating Stainless Steels (Stainless Heat Treat Tips) | Focused guide on martensitic stainless knife steels: preventing decarb, avoiding sensitization, and achieving maximum corrosion resistance. (Internal) |
| Knife Testing Protocols (Performance Testing Handbook) | Our internal protocols for testing blade hardness, flexibility, sharpness (including CATRA), and corrosion – ensuring reliability before release. (Internal) |
About the Author: Yashar Mousavand
Yashar Mousavand is a bushcraft instructor and field practitioner who focuses on how knife performance is built from process control: forging temperature discipline, microstructure management, and repeatable heat treatment. His work combines hands on wilderness use with shop verification, including hardness checks, geometry measurement, and documented test protocols to connect steel choices and heat treat decisions to real failure modes like chipping, rolling, warping, and corrosion.
On Yashar Survival Academy, he publishes technical guides that prioritize measurable parameters, manufacturer heat treat data, and transparent revision standards. Each article is written to help makers and serious users understand not only what works, but why it works, with clear limits, process notes, and practical controls that can be reproduced in a small workshop.
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